Preheat oven to 375° F (190° C). Brush bottom of pie crust with egg white and bake for 5 min. Refrigerate for 5 min. Brush bottom of crust with melted chocolate. Refrigerate until needed.
Beat cream in a medium bowl using an electric mixer (stand or hand-held) until soft peaks form. Add brown sugar, vanilla, cinnamon and cream cheese. Pour cream into pie crust and refrigerate for 2 hours.
Preheat barbecue to medium-high. Place a sheet of aluminum foil over half the grill. Brush peaches and pepper with oil. Place peaches on foil and grill for 3 to 5 min., turning once. Meanwhile, place pepper directly on the grill and cook for 1 to 2 min. per side. Remove peaches and pepper from barbecue and let cool. Seed and finely dice pepper and toss with jam and butter in a large bowl. Slice peaches into 6 to 8 pieces and add to mixture. Gently fold in raspberries. Top pie with fruit mixture, drizzle with more melted chocolate if desired and serve immediately.
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